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Adsorptive Removal of Synthetic Organic Compounds in Aqueous Solutions by Fresh Nipa Palm Fronds

Received: 3 January 2024     Accepted: 15 January 2024     Published: 1 February 2024
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Abstract

Adsorptive removal of contaminants in wastewater is distinctive because the technique is simple, effective and with low cost, however, the flexibility of the adsorption process is actually contingent on the sorption abilities of the adsorbent. Nipa palm has been tested in several studies to be effective due to its porous structure and surface properties. Hence, the objective of this paper was to evaluate the adsorptive removal of synthetic organic compounds (SOCs) in aqueous solutions using carbonized and surface-modified carbons produced from Nipa Palm (Nypa Fruticans Wurmb) fronds using chemical oxygen demand (COD) as the index of measurement. Data obtained for the present investigation revealed that percent COD reduction of SOCs by the carbons ranged between 93.81 – 96.67%, while COD reduction capacity estimated by Langmuir-type model was between 1.77 - 11.83 mg/g at ambient temperature and at an optimum pH of 8.5. Thermodynamic assessment by Gibbs free energy (∆Go, KJ/mol) revealed that ∆Go values were negative (from - 1.45 KJ/mol to - 5.89 KJ/mol). The results obtained show that Nipa palm could be a beneficial source for the development of an eco-friendly and locally available activated carbon for removal of organic contaminants from domestic and industrial wastewaters.

Published in Science Frontiers (Volume 5, Issue 1)
DOI 10.11648/sf.20240501.13
Page(s) 13-23
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Synthetic Organic Compounds, Chemical Oxygen Demand, Adsorption, Nipa Palm, Carbonized Carbon, Wastewater

References
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[2] Adowei, P; Abia, A. A; & Spiff, A. I (2015). Physicochemical Characteristics of Biocarbons obtained from Nipa Palm (Nypa Fruiticans Wurmb) Leaves. Research. Journal of Chemical Sciences. Volume 5 No. 1, pp 18-26.
[3] Adowei, P; Wariboko, E & Markmanuel, D, (2020). Removal of Low concentration of. Kerosene from water using Nipa paim (Nypa Fruticans Wurmb) fruit fibre. International Journal of Research Volume 8 No. 6 pp 1-9.
[4] Adowei, P; & Abia A. A (2016). Chemical Oxygen Demand (COD) Attenuation of Methyl Red in Water using Biocarbons obtained from Nipa palm (Nypa fruticans Wurmb) Leaves. Journal of Applied Sciences & Environmental Management. Volume 20 No. 4 pp 1163-1176.
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[7] Horsfall, M. Jnr & Abia, A. A (2003). Sorption of Cd (II) and Zn (II) ions from Aqueous solutions by Cassava Waste Biomass (Manihot sculenta Cranz). Wat. Res. 37: 4913–4923.
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[10] Horsfall, M. Jnr & Spiff, A. I. (2005) a. Effect of metal ion concentration on the biosorption of Pb2+ and Cd2+ by Caladium bicolor (wild cocoyam). African J. of Biotech. Vol. 4(2) pp 191-196.
[11] Abechi, S. E, Gimba, C E, Uzairu, A, & Dallatu, Y A (2013). Preparation and Characterization of activated carbon from Palm Kernel Shell by Chemical Activation. Research Journal of Chemical Sciences. 3(7) 54-61.
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[25] Wankasi, D., Horsfall, M. Jnr; & Spiff, A. I., (2005). Desorption of Pb2+ and Cu2+ from Nipa palm (Nypa fruticans Wurmb) biomass. Afr. J. Biotechnol. 4, 923-927.
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Cite This Article
  • APA Style

    Adowei, P. (2024). Adsorptive Removal of Synthetic Organic Compounds in Aqueous Solutions by Fresh Nipa Palm Fronds. Science Frontiers, 5(1), 13-23. https://doi.org/10.11648/sf.20240501.13

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    ACS Style

    Adowei, P. Adsorptive Removal of Synthetic Organic Compounds in Aqueous Solutions by Fresh Nipa Palm Fronds. Sci. Front. 2024, 5(1), 13-23. doi: 10.11648/sf.20240501.13

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    AMA Style

    Adowei P. Adsorptive Removal of Synthetic Organic Compounds in Aqueous Solutions by Fresh Nipa Palm Fronds. Sci Front. 2024;5(1):13-23. doi: 10.11648/sf.20240501.13

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  • @article{10.11648/sf.20240501.13,
      author = {Pereware Adowei},
      title = {Adsorptive Removal of Synthetic Organic Compounds in Aqueous Solutions by Fresh Nipa Palm Fronds},
      journal = {Science Frontiers},
      volume = {5},
      number = {1},
      pages = {13-23},
      doi = {10.11648/sf.20240501.13},
      url = {https://doi.org/10.11648/sf.20240501.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.sf.20240501.13},
      abstract = {Adsorptive removal of contaminants in wastewater is distinctive because the technique is simple, effective and with low cost, however, the flexibility of the adsorption process is actually contingent on the sorption abilities of the adsorbent. Nipa palm has been tested in several studies to be effective due to its porous structure and surface properties. Hence, the objective of this paper was to evaluate the adsorptive removal of synthetic organic compounds (SOCs) in aqueous solutions using carbonized and surface-modified carbons produced from Nipa Palm (Nypa Fruticans Wurmb) fronds using chemical oxygen demand (COD) as the index of measurement. Data obtained for the present investigation revealed that percent COD reduction of SOCs by the carbons ranged between 93.81 – 96.67%, while COD reduction capacity estimated by Langmuir-type model was between 1.77 - 11.83 mg/g at ambient temperature and at an optimum pH of 8.5. Thermodynamic assessment by Gibbs free energy (∆Go, KJ/mol) revealed that ∆Go values were negative (from - 1.45 KJ/mol to - 5.89 KJ/mol). The results obtained show that Nipa palm could be a beneficial source for the development of an eco-friendly and locally available activated carbon for removal of organic contaminants from domestic and industrial wastewaters.
    },
     year = {2024}
    }
    

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    T1  - Adsorptive Removal of Synthetic Organic Compounds in Aqueous Solutions by Fresh Nipa Palm Fronds
    AU  - Pereware Adowei
    Y1  - 2024/02/01
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    N1  - https://doi.org/10.11648/sf.20240501.13
    DO  - 10.11648/sf.20240501.13
    T2  - Science Frontiers
    JF  - Science Frontiers
    JO  - Science Frontiers
    SP  - 13
    EP  - 23
    PB  - Science Publishing Group
    SN  - 2994-7030
    UR  - https://doi.org/10.11648/sf.20240501.13
    AB  - Adsorptive removal of contaminants in wastewater is distinctive because the technique is simple, effective and with low cost, however, the flexibility of the adsorption process is actually contingent on the sorption abilities of the adsorbent. Nipa palm has been tested in several studies to be effective due to its porous structure and surface properties. Hence, the objective of this paper was to evaluate the adsorptive removal of synthetic organic compounds (SOCs) in aqueous solutions using carbonized and surface-modified carbons produced from Nipa Palm (Nypa Fruticans Wurmb) fronds using chemical oxygen demand (COD) as the index of measurement. Data obtained for the present investigation revealed that percent COD reduction of SOCs by the carbons ranged between 93.81 – 96.67%, while COD reduction capacity estimated by Langmuir-type model was between 1.77 - 11.83 mg/g at ambient temperature and at an optimum pH of 8.5. Thermodynamic assessment by Gibbs free energy (∆Go, KJ/mol) revealed that ∆Go values were negative (from - 1.45 KJ/mol to - 5.89 KJ/mol). The results obtained show that Nipa palm could be a beneficial source for the development of an eco-friendly and locally available activated carbon for removal of organic contaminants from domestic and industrial wastewaters.
    
    VL  - 5
    IS  - 1
    ER  - 

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Author Information
  • Department of Pure and Industrial Chemistry, University of Port Harcourt, Port Harcourt, Nigeria

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